Novel preparation and high electrical performance effect of Mn-doped ultra-high surface area activated carbon (USAC) as an additive for Ni hybrid capacitors

This paper reports the synthesis of various molar concentrations of manganese (Mn)-doped Ultra-High Surface area Activated Carbon (USAC) additives and their efficient use as cathode materials for supercapacitors. We synthesized the nanoparticles via a novel and facile dip-coating process and characterized them in detail by various analytical techniques. The SEM, EDAX, and XPS results showed that the Mn ions were successfully substituted on the USAC additives’ layered structure without any structural changes. The long cyclic stability of the as-prepared Mn-doped USAC additives was tested as a cathode material for supercapacitors at different current densities. The detailed experimental results showed that the Mn dopant content crucially determines the electrochemical performances of the USAC additives. Electrochemical measurements showed that the MnCEP-S600HTT with 0.10 mol% molar concentration of Mn dopant gives the best cycling performances. It delivers a discharge capacity of 262.9 mAh g^?1 after 100 cycles. Further increasing the current density to 1000 mA g^?1 allowed it to still maintain 253.6 mAh g^?1 after 200 cycles. We confirmed that the structure of Mn-doped USAC additives is an important pole to improve the structural stability and electrochemical properties.     

炼铁-炼钢界面布局紧凑模式

论述了炼铁-炼钢界面的紧凑衔接技术,涉及多维物质流的衔接、传递、匹配及缓冲等过程。从各角度综合分析得出,该界面衔接布置紧凑,占地面积小,实施MES系统的“在线铁水罐跟踪系统”使炼铁-炼钢界面减少了铁水罐周转个数,相对传统方式的铁水包输运方式,保温剂使用量平均减少了0.483 kg/t(铁),铁水入炉温度提高约60 ℃。同时,确保了100%的“一罐到底”命中率,大幅节省了耐材费用,具有显著的经济效益和社会效益。     

掘进工作面瓦斯分级治理的技术研究

余吾煤业公司作为高瓦斯矿井,瓦斯吸附能力强,属低透气性难抽放煤层。矿井目前处于新旧采区重叠期、瓦斯含量双向变化重叠期,需要立足当前、分类施策,提升采掘效率。为进一步规范掘进工作面瓦斯治理,建立规范的瓦斯治理程序,介绍了掘进工作面瓦斯分级治理相关措施,确保掘进工作面安全生产有序进行。     

Waste sugar solution polymer-derived N-doped carbon spheres with an ultrahigh specific surface area for superior performance supercapacitors

Waste sugar solution (WSS), a waste by-product of manufacturing vitamin C, contains abundant waste acids and organics. In this work, a N/O-enriched copolymer was synthesized via a facile polymerization via the hydrogen bonding of O-containing functional groups and melamine and the crosslinking of aldehyde groups. Subsequently, N-doped carbon spheres were prepared by a typical carbonation/activation method. Remarkably, benefiting from an ultrahigh specific surface area (3612 m²/g) and rich heteroatom content (4.3% for N, 8.8% for O), the carbon spheres deliver a high specific capacitance of 387 F/g at 50 mA/g and 283 F/g at 5 A/g with 6 M KOH in two-electrode system. The assembled symmetric electric double-layer capacitor exhibits high energy density of 10.83 Wh/kg at 11.10 W/kg. This research provides a facile method for preparing N/O-doped carbon spheres by WSS, and confirms the excellent electrochemical performance of WSS-derived carbons in energy storage applications.     

窑街矿区冲击地压防治技术

冲击地压是煤矿重大灾害之一,窑街矿区的3对矿井先后被评价为冲击地压矿井,经过分析和研究,该矿区冲击地压发生机理为厚硬顶板破断产生大能量震动,静载应力集中和矿震动载扰动叠加作用。依据冲击地压机理制定了冲击地压治理技术方案,矿区冲击地压发生的频率和能量得到有效控制,为矿井安全生产提供了保障。     

A graphical method of presenting property rights,building types,and residential behaviors: A case study of Xiaoxihu historic area,Nanjing

One of the main reasons for the decline of urban historic areas in China is the co-existence of multiple property rights. It also deeply affects conservation and regeneration practice. This paper aims to propose a graphical method that illustrates the association between property rights, space, and resident behavior. Based on typological maps and justified graphs, a three-step method was proposed to visualize the relationships between these three elements. The final graph and quantitative data were used to observe the evolution of the courtyard building from a diachronic perspective, as well as to compare the residential behavior in different types from a synchronic perspective. The results show that following the subdivision of property rights, the building layout become more diverse due to various illegal additions, while the residential behavior within different building types tends to be consistent. Moreover, the study observed the traditional Chinese courtyard buildings’ adaptability. The findings contribute to understand the evolution of Chinese urban historic areas and internal motivation, and provide guidance for the conservation and regeneration practice.     

A lattice Boltzmann exploration of two-phase displacement in 2D porous media under various pressure boundary conditions

While experimental designs developed in recent decades have contributed to research on dynamic nonequilibrium effects in transient two-phase flow in porous media, this problem has been seldom investigated using direct numerical simulation (DNS). Only a few studies have sought to numerically solve Navier–Stokes equations with level-set (LS) or volume-of-fluid (VoF) methods, each of which has constraints in terms of meniscus dynamics for various flow velocities in the control volume (CV) domain. The Shan–Chen multiphase multicomponent lattice Boltzmann method (SC-LBM) has a fundamental mechanism to separate immiscible fluid phases in the density domain without these limitations. Therefore, this study applied it to explore two-phase displacement in a single representative elementary volume (REV) of two-dimensional (2D) porous media. As a continuation of a previous investigation into one-step inflow/outflow in 2D porous media, this work seeks to identify dynamic nonequilibrium effects on capillary pressure–saturation relationship (P_c–S) for quasi-steady-state flow and multistep inflow/outflow under various pressure boundary conditions. The simulation outcomes show that P_c, S and specific interfacial area (a_nw) had multistep-wise dynamic effects corresponding to the multistep-wise pressure boundary conditions. With finer adjustments to the increase in pressure over more steps, dynamic nonequilibrium effects were significantly alleviated and even finally disappeared to achieve quasi-steady-state inflow/outflow conditions. Furthermore, triangular wave-formed pressure boundary conditions were applied in different periods to investigate dynamic nonequilibrium effects for hysteretical P_c–S. The results showed overshoot and undershoot of P_c to S in loops of the nonequilibrium hysteresis. In addition, the flow regimes of multistep-wise dynamic effects were analyzed in terms of Reynolds and capillary numbers (Re and Ca). The analysis of REV-scale flow regimes showed higher Re (1 < Re < 10) for more significant dynamic nonequilibrium effects. This indicates that inertia is critical for transient two-phase flow in porous media under dynamic nonequilibrium conditions.